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Göran Hilmersson
Dekan
Naturvetenskapliga fakultetsstyrelsenProfessor
Institutionen för kemi och molekylärbiologiOm Göran Hilmersson
Kontaktinformation: Kemihuset Kemivägen 10, rumsnummer 8075 Lundberglaboratoriet, Medicinaregatan 9, rumsnummer XXX FORSKNING Metodutveckling inom organisk syntes Vår forskning har tidigare inbegripit mekanistiska undersökningar i syfte att öka förståelsen kring struktur, dynamik och reaktivitet hos litiumorganiska reagens. I dessa studier har NMR spektroskopi vid låg temperatur varit ett viktigt instrument. Specifikt har forskningen fokuserat på förståelsen för hur kirala litiumreagens kan användas i asymmetrisk syntes. En annan gren av vår forskning har varit utveckling av ny kemi med samarium dijodid. Vi har utvecklat ny användbar syntesmetodik för snabba reduktionsreaktioner med reagenset SmI2/amin/vatten. Vidare har vi också utvecklat lantanidmedierade reaktioner där vi selektivt och effektivt kunnat substituera den starka kol-fluor bindningen med kol-jod eller kol-kväve bindningar.
Publikationer ResearcherID: www.researcherid.com/rid/D-3468-2009
Google Scholar: https://scholar.google.se/citations?user=SYJ6AeMAAAAJ&hl=en
UNDERVISNING • Avancerad organisk kemi (KEM815) • Avancerad organisk syntes (KEM750)
UPPDRAG • Prefekt: Institutionen för Kemi och molekylärbiologi
MERITER Göran Hilmersson studerade organisk kemi vid Göteborgs universitet och disputerade 1996. Efter en Wallenbergfinansierad postdok vid The Scripps Research Institute återvände han till Göteborg som forskarassistent 1998. Han blev befordrad till universitetslektor 1999 och erhöll en rådsforskartjänst från Vetenskapsrådet 2004. Sedan 2005 är han professor i organisk kemi.
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Utilizing a needle as a source of iron in synergistic dual photoredox catalytic generation of alkoxy
radicals
Alica Ondrejkova, Rickard Lindroth, Göran Hilmersson, Carl Johan Wallentin
Chemical Communications - 2022 -
Enantioselective deprotometalation of alkyl ferrocenecarboxylates using bimetallic
bases
G. Dayaker, W. Erb, M. Hedidi, F. Chevallier, M. Blot, P. C. Gros, Göran Hilmersson, T. Roisnel, V. Dorcet, G. Bentabed-Ababsa, F. Mongin
New Journal of Chemistry - 2021 -
Catalytic Iodination of the Aliphatic C-F Bond by YbI3(THF)(3): Mechanistic Insight and Synthetic
Utility
Mario Janjetovic, Andreas Ekebergh, Annika M. Träff, Göran Hilmersson
Organic Letters - 2016 -
C-F bond substitution via aziridinium ion
intermediates
Annika M. Träff, Mario Janjetovic, Göran Hilmersson
Chemical Communications - 2015 -
Mild and Selective Activation and Substitution of Strong Aliphatic C-F
Bonds
Mario Janjetovic, Annika M. Träff, Göran Hilmersson
Chemistry-a European Journal - 2015 -
Solvent-Dependent Substrate Reduction by (Sm N(SiMe3)(2) (2)(THF)(2)}. An Alternative Approach for Accelerating the Rate of Substrate Reduction by
Sm(II)
T. V. Chciuk, Göran Hilmersson, R. A. Flowers
Journal of Organic Chemistry - 2014 -
Selective C-F Bond Activation: Substitution of Unactivated Alkyl Fluorides using
YbI3
Annika M. Träff, Mario Janjetovic, Linda Ta, Göran Hilmersson
Angewandte Chemie-International Edition - 2013 -
Selective cleavage of 3,5-bis-(trifluoromethyl)benzylcarbamate by
SmI2-Et3N-H2O
Tobias Ankner, Anna Said Stålsmeden, Göran Hilmersson
Chemical Communications - 2013 -
Metalated nitriles: N- and C-coordination preferences of Li, Mg, and Cu
cations
M. Purzycki, W. Liu, Göran Hilmersson, F. F. Fleming
Chemical Communications - 2013 -
Solvent dependent reductive defluorination of aliphatic C-F bonds employing
Sm(HMDS)(2)
Mario Janjetovic, Annika M. Träff, Tobias Ankner, Jenny Wettergren, Göran Hilmersson
Chemical Communications - 2013 -
Introduction of a new single electron transfer sensitive protecting
group
Göran Hilmersson, Tobias Ankner
ACS National Meeting, San Diego, CA, March 25- 29 2012 - 2012 -
Enantioselective Metalation of N,N-Diisopropylferrocenecarboxamide and Methyl Ferrocenecarboxylate Using Lithium-Metal Chiral
Bases
G. Dayaker, D. Tilly, F. Chevallier, Göran Hilmersson, P. C. Gros, F. Mongin
European Journal of Organic Chemistry - 2012 -
Aggregation and Solvation of Chiral N,P-Amide Ligands in Coordinating Solvents: A Computational and NMR Spectroscopic
Study
Petra Rönnholm, Sten O. Nilsson Lill, Jürgen Gräfenstein, Per-Ola Norrby, Mariell Pettersson, Göran Hilmersson
Chempluschem - 2012 -
A computational study of the enantioselective addition of n-BuLi to benzaldehyde in the presence of a chiral lithium N,P
amide.
Petra Rönnholm, Jürgen Gräfenstein, Per-Ola Norrby, Göran Hilmersson, Sten O. Nilsson Lill
Organic & biomolecular chemistry - 2012 -
NMR studies of chiral lithium amides with phosphine chelating groups reveal strong Li-P-interactions in ethereal
solvents
Petra Rönnholm, Göran Hilmersson
ARKIVOC - 2011 -
Selective alpha-defluorination of polyfluorinated esters and amides using
SmI2/Et3N/H2O
Jenny Wettergren, Tobias Ankner, Göran Hilmersson
CHEMICAL COMMUNICATIONS - 2010 -
Asymmetric Deprotonation using s-BuLi or i-PrLi and Chiral Diamines in THF: The Diamine
Matters
Giorgio Carbone, Peter O''Brien, Göran Hilmersson
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY - 2010 -
Spontaneous Resolution and Carbonation of Chiral Benzyllithium
Complexes
Anders Lennartson, Jonas Sundberg, Tove Wiklund, Göran Hilmersson, Mikael Håkansson
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY - 2010 -
KHMDS enhanced SmI(2)-mediated reformatsky type
alpha-cyanation.
Tobias Ankner, Maria Fridén-Saxin, Nils Pemberton, Tina Seifert, Morten Grøtli, Kristina Luthman, Göran Hilmersson
Organic letters - 2010 -
SmI2/H2O/amine promoted reductive cleavage of benzyl-heteroatom bonds: optimization and
mechanism
Tobias Ankner, Göran Hilmersson
TETRAHEDRON - 2009 -
Instantaneous Deprotection of Tosylamides and Esters with
SmI2/Amine/Water
Tobias Ankner, Göran Hilmersson
Organic Letters - 2009 -
Instantaneous SmI2/H2O/amine mediated reduction of nitroalkanes and alpha,beta-unsaturated
nitroalkenes
Tobias Ankner, Göran Hilmersson
Tetrahedron Letters - 2007 -
Improved and efficient synthesis of chiral N,P-Ligands via cyclic sulfamidates for asymmetric addition of butyllithium to
benzaldehyde
Petra Rönnholm, Mikael Södergren, Göran Hilmersson
Organic Letters - 2007 -
Studies of complexes between phenyllithium and (-)-sparteine in ether
solutions
Richard Sott, Mikael Håkansson, Göran Hilmersson
Organometallics - 2006 -
Correlation between the 6Li,15N coupling constant and the coordination number at
lithium.
Johan Granander, Richard Sott, Göran Hilmersson
Chemistry (Weinheim an der Bergstrasse, Germany) - 2006 -
Highly enantioselective 1,2-additions of various organolithium reagents to
aldehydes
Johan Granander, Jonas Eriksson, Göran Hilmersson
Tetrahedron-Asymmetry - 2006 -
Estimating the limiting reducing power of SmI2/H2O/amine and YbI2/H2O/amine by efficient reduction of unsaturated
hydrocarbons.
Anders Dahlén, Åke Nilsson, Göran Hilmersson
The Journal of organic chemistry - 2006 -
Structures and Dynamics of Chiral Lithium
Amides
Johan Granander, Göran Hilmersson
The Patai series: The chemistry of Organolithium Compounds: R-Li, Part 2 - 2005 -
Reduction of beta-hydroxyketones by
SmI2/H2O/Et3N.
Todd A Davis, Pramod R Chopade, Göran Hilmersson, Robert A Flowers
Organic letters - 2005 -
Exploring SmBr2-, SmI2-, and YbI2-mediated reactions assisted by microwave
irradiation.
Anders Dahlén, Edamana Prasad, Robert A Flowers, Göran Hilmersson
Chemistry (Weinheim an der Bergstrasse, Germany) - 2005 -
Kinetic and NMR spectroscopic studies of chiral mixed sodium/lithium amides used for the deprotonation of cyclohexene
oxide.
Richard Sott, Johan Granander, Carl Williamson, Göran Hilmersson
Chemistry (Weinheim an der Bergstrasse, Germany) - 2005 -
Mechanistic study of the SmI2/H2O/amine-mediated reduction of alkyl halides: amine base strength (pKBH+) dependent
rate.
Anders Dahlén, Göran Hilmersson
Journal of the American Chemical Society - 2005 -
Solution structures of chiral lithium amides with internal sulfide coordination: sulfide versus ether coordination in chiral lithium
amides
Richard Sott, Johan Granander, Peter Dinér, Göran Hilmersson
Tetrahedron-Asymmetry - 2004 -
Microwave-assisted generation of lanthanide(II) halides in THF and simple quantitative
determination
Anders Dahlén, Göran Hilmersson
European Journal of Inorganic Chemistry - 2004 -
Samarium(II) iodide mediated reductions - Influence of various
additives
Anders Dahlén, Göran Hilmersson
European Journal of Inorganic Chemistry - 2004 -
Microwave assisted synthesis of lanthanide reagents (Sml(2), SmBr2, Ybl(2), and Eul(2) and their use in various reduction
reactions
Göran Hilmersson, Anders Dahlén
Abstracts of Papers of the American Chemical Society - 2004 -
Mixed complexes formed by lithioacetonitrile and chiral lithium amides: observation of (6)li,(15)N and (6)Li,(13)C couplings due to both C-Li and N-Li
contacts.
Richard Sott, Johan Granander, Göran Hilmersson
Journal of the American Chemical Society - 2004 -
Chiral cis-octahedral Grignard
reagents
Mikael Håkansson, Marcus Vestergren, J Eriksson, Göran Hilmersson
Journal of Organometallic Chemistry - 2003 -
Giving phenyllithium a right-handed double-helical twist. Syntheses and crystal structures of enantiopure alkyl-, aryl-, and amidolithium
aggregates
Mikael Håkansson, Marcus Vestergren, J Eriksson, Göran Hilmersson
Journal of Organometallic Chemistry - 2003